The Internal Axial Ligand of Hydroperoxy-Co(III)-Bleomycin: 1H-15N HSQC NMR investigation of Bleomycin, Deglycobleomycin, and their Hydroperoxy-Co(III) Complexes.

• Introduction
• N-15 NMR chemical shifts
• Three dimensional structure using NOE and C-H coupling constants
• Literature

Literature

1. Zhao, C.; Xia, C.; Mao, Q.; Försterling, F. H.; DeRose, E.; Antholine, W.E.; Subczynski, W.K.; Petering, D.H.; J. Inorg Biochem 2002, 91(1), 259-268.
2. Wu, W. et. al.; J. Am. Chem. Soc. 1996, 118, 1268-1280.
3. Caceres-Cortes et. al.; Eur. J. Biochem. 1997, 244, 818-828.
4. Xia, C.; Försterling, F. H.; Petering, D. H., submitted to Biochemistry
5. Juranic, N. et. al; J. Inorg. Biochem. 1996, 62, 117-126.
6. Williamson, R. T.; Magn. Res. Chem. 2000, 38, 265-273.
7. Mulloy et al.; Carbohydr. Res. 1988, 184, 39-46.

Acknowledgements